Abstract
4-Chloroaniline (4ClAni) in the presence of zinc oxide (ZnO) nanoparticles were prepared by chemical oxidative polymerization in hydrochloric acid solution using Ammonium persulfate as oxidant. The effects of amount of ZnO nanoparticles (1, 1.5, 2, 2.5 and 3 g, respectively) on the properties of products were investigated. The obtained nanocomposites was characterized using XRD, IR, UV–visible, and XPS which confirmed the incorporation of the nanoparticle ZnO in the P(4ClAni) matrix and the maximum interaction occurs for 2 g ZnO loading. The TGA analysis was used to confirm the thermal stability and number of water molecules in each nanocomposites chain unit. Although the incorporation of ZnO nanoparticles reduces the electric conductivity of the P(4ClAni), the resulting nanocomposites still keep high conductivities, ranging between 2.19 × 10−2 and 5.92 × 10−4 S cm−1. Good electrochemical response has been observed for samples of amounts ZnO less than 2 g; the observed redox processes indicate that the polymerization on ZnO nanoparticles produces electroactive polymers. The P(4ClAni) layer adhered well to the ZnO nanoparticles and can be used as practical applications.
Similar content being viewed by others
References
J. Anand, S. Palaniappan, D.N. Sathyanarnayana, Prog. Polym. Sci. 23, 993 (1998)
Z. Ruan, W. Rong, Q. Lim, Z. Li, J. Inorg. Organomet. Polym Mater. 25, 98 (2015)
B.I. Nandapure, S.B. Kondawar, A.I. Nandapure, in Proceedings of International Conference on Benchmarks in Engineering Science and Technoly (ICBEST’12) (2012)
S.L. Patil, M.A. Chougule, S.G. Pawar, S. Sen, V.B. Patil, Soft Nanosci. Lett. 2, 46 (2012)
U. Ozgur, Y.I. Alivov, C. Liu, A. Teke, M.A. Reshchikov, S. Dogan, V. Avrutin, S.J. Cho, H. Morkoc, J. Appl. Phys. 98, 4130 (2005)
A.L. Stroyuk, V.V. Shvalagin, SYa. Kuchmii, J. Photochem. Photobiol. A Chem. 173, 185 (2005)
Y. Li, W. Xie, X. Hu, G. Shen, X. Zhou, Y. Xiang, X. Zhao, P. Fang, Langmuir 26, 591 (2010)
Y. He, Appl. Surf. Sci. 249, 1 (2005)
N. Gospodinova, L. Terlemezyan, Prog. Polym. Sci. 23, 1443 (1998)
I. Toumi, A. Benyoucef, A. Yahiaoui, C. Quijada, E. Morallon, J. Alloy. Compd. 551, 212 (2013)
A.K. Zak, M.E. Abrishami, W.H. Majid, R. Abd Yousefi, S.M. Hosseini, Ceram Int. 37, 393 (2011)
J. Tang, X. Jing, B. Wang, F. Wang, Synth. Met. 24, 231 (1998)
A. Mostafaei, F. Nasirpouri, Prog. Org. Coat. 77, 146 (2014)
A.B. Dehkordi, J. Moghaddam, A. Mostafaei, Mater. Res. Bull. 48, 4235 (2013)
S.K. Shukla, A. Tiwari, G.K. Parashar, A.P. Mishra, G.C. Dubey, Talanta 80, 565 (2009)
O. Misoon, K. Seok, Electrochim. Acta 59, 196 (2012)
H.K. Chaudhari, D.S. Kelkar, Polym. Int. 42, 380 (1997)
S.W. Phang, M. Tadokoro, J. Watanabe, N. Kuramoto, Synth. Met. 158, 251 (2008)
C.D. Wagner, W.M. Riggs, L.E. Davis, J.F. Moulder, G.E. Muilenberg (eds.), Handbook of X-ray Photoelectron Spectroscopy (Perkin-Elmer, Eden Prairie, 1979)
A. Qaiser, M. Hyland, D. Patterson, Synth. Met. 162, 958 (2012)
K. Tan, B. Tan, J. Chem. Phys. 94, 5382 (1991)
A. Paphanassiou, J. Phys. D Appl. Phys. 35, L88 (2002)
D.A. Seanor, Electrical Properties of Polymers (Academic Press, New York, 1982), pp. 2–3
R.H. Gonclaves, W.H. Schreiner, E.R. Leite, Langmuir 26, 11657 (2010)
H. Sozeri, U. Kurtan, R. Topkaya, A. Baykal, M.S. Toprak, Ceram. Int. 39, 5137 (2013)
L.S.N.E. Mirhashemi, M. Rabbani, S.M.H.E. Mirhashemi, R. Rahimi, E. Asadi, S. Azodi-Deilami, J. Alloy. Compd. 646, 1157 (2015)
R. Gangopadhyay, A. De, Eur. Polym. J. 35, 1985 (2000)
I. Radja, H. Djelad, E. Morallon, A. Benyoucef, Synth. Met. 202, 25 (2015)
F. Chouli, I. Radja, E. Morallon, A. Benyoucef, Polym. Compos. (2015). doi:10.1002/pc.23837
F.Z. Dahou, M.A. Khaldi, A. Zehhaf, A. Benyoucef, M.I. Farrahi, Adv. Polym. Technol. (2015). doi:10.1002/adv.21566
S. Cho, J.S. Lee, J. Jun, J. Jang, J. Mater. Chem. A 2, 1955 (2014)
J.E. Park, S.G. Park, A. Koukitu, O. Hatozaki, N. Oyama, Synth. Met. 141, 265 (2004)
Acknowledgments
The authors wish to acknowledge the directorate General of Scientific Research and Technological Development (DGRSDT) and the support of CNEPRU through the Project CNEPRU/E-03720130015 (Algeria). They also thank Prof Emilia Morallon of Instituto Universitario de Materiales, Alicante University (Spain) for the EDX analysis. The authors thank the anonymous reviewers for their critical inputs which have significantly helped in improving the manuscript.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Bekhoukh, A., Zehhaf, A., Benyoucef, A. et al. Nanoparticules Mass Effect of ZnO on the Properties of Poly(4-Chloroaniline)/Zinc Oxide Nanocomposites. J Inorg Organomet Polym 27, 13–20 (2017). https://doi.org/10.1007/s10904-016-0433-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10904-016-0433-4